Location: If you keep in touch with Shinra intern Chadley during Chapter 8, he should provide you with a VR combat scenario that pits you against summon creature Shiva to earn its respective Materia. Chadley can be found standing between a healing bench and the Materia shop in the Sector 5 Slums.
As a note, you'll have whoever's in your party when you take on this fight, so if you try it with just Cloud, it'll be tougher than if you tackle it with Aerith in your squad. We recommend that you bring Aerith along, though.
Boss Strategy: Shiva is an Ice summon, and thus weak to Fire. Give Aerith your best Fire Materia, and make sure you have the Ifrit summon equipped, then head into the battle. Cloud can pretty much take care of himself, so you're better off controlling Aerith to run up her ATB bars as quickly as possible; the more Fire or Fira spells you can cast on Shiva, the faster you'll manage to stagger her. Make use of Aerith's Arcane Ward ability, which automatically makes you cast two spells for every ATB bar you spend, to maximize your damage. A good Fire spell will knock Shiva to the ground, offering Cloud a chance to lay down some melee attacks. Make sure you're not too close when she gets back up, though, because she'll use the Icicle Impact area attack spell around her when she's back on her feet.
You'll want to keep laying down spells on Shiva while working to keep Aerith alive. You'll need to be on top of dodging her attacks to stay clear of incoming danger, which include Blizzara spells that Shiva will shoot your way and a bunch of ice crystals to shoot at you in a group. Dodging the ice crystals attack is a losing battle because there are so many of them, so guard against it and power through.
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